Building block syntheses of site-isolated vanadyl groups in silicate oxides.
نویسندگان
چکیده
Cross-linking of the cubic silicate building block, Si8O20 with vanadyl chloride leads to porous solids in which a homogeneous dispersion of isolated vanadyl groups is maintained throughout the matrix even at high loadings of vanadium.
منابع مشابه
A hierarchically ordered porous novel vanado-silicate catalyst for highly efficient oxidation of bulky organic molecules.
A novel hierarchically ordered porous vanado-silicate nanocomposite with interconnecting macroporous windows and meso-microporous walls containing well dispersed vanadyl species has been fabricated and used as a heterogeneous catalyst for the oxidation of a bulky organic molecule, namely cyclooctene.
متن کاملBlock Copolymer Templating Syntheses of Mesoporous Metal Oxides with Large Ordering Lengths and Semicrystalline Framework
A simple and general procedure has been developed for the syntheses of ordered largepore (up to 14 nm) mesoporous metal oxides, including TiO2, ZrO2, Nb2O5, Ta2O5, Al2O3, SiO2, SnO2, WO3, HfO2, and mixed oxides SiAlOy, Al2TiOy, ZrTiOy, SiTiOy, ZrW2Oy. Amphiphilic poly(alkylene oxide) block copolymers were used as structure-directing agents in nonaqueous solutions for organizing the network-form...
متن کاملStatistical Optimization of Liquid Phase Oxidation of Benzyl Alcohol over Efficient Cobalt Promoted Vanadyl Pyrophosphate Catalysts by Box-Behnken Design
Vanadium phosphorus oxides (VPO) has been applied as a heterogeneous catalyst in gas phase oxidation reactions and its application is very limited in liquid phase. In this study a series of cobalt-doped vanadium phosphorus oxides (VPO-Co) catalysts with different loading of Co (0.01-1.0 mol ratio of Co/V) were prepared. Oxidation of benzyl alcohol was studied in the liquid phase over VPO and VP...
متن کاملβ-Nb9VO25
The title compound, nona-niobium vanadium penta-cosa-oxide, was prepared by a solid-state reaction at 1198 K. It is isotypic with Nb9AsO25, Nb9PO25 and Ta9VO25. The structure consists of NbO6 octa-hedra (one with 4/m.. and two with m.. symmetry) and VO4 tetra-hedra (-4.. symmetry) sharing corners and edges to form a three-dimensional framework. This framework can be considered as a junction bet...
متن کاملEffect of Vanadyl Sulfate on Fructose-Induced Insulin Resistance Rat
Insulin resistance syndrome, also referred to as the metabolic syndrome or syndrome X, refers to a constellation of common metabolic and cardiovascular disorders (e.g. obesity, type 2 diabetes mellitus, hypertension, and dyslipidemia), which are all cardiovascular risk factors. Insulin resistance can be induced by fructose-rich diet in rats. We investigated the effect of vanadyl sulfate (0.2 mg...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 7 شماره
صفحات -
تاریخ انتشار 2004